Bis-(1,5-cyclooctadiene)-rhodium trifluoromethanesulfonate
Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
CAS: 99326-34-8
Molecular Formula: C17H24F3O3RhS
Bis-(1,5-cyclooctadiene)-rhodium trifluoromethanesulfonate - Names and Identifiers
| Name | Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate |
| Synonyms | rhodium trifluoromethanesulfonate (1Z,5Z)-cycloocta-1,5-diene Bis-(1,5-cyclooctadiene)-rhodium trifluoromethanesulfonate BIS(1,5-CYCLOOCTADIENE)-TRIFLUOROMETHANESULFITORHODIUM (I) BIS(1,5-CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate |
| CAS | 99326-34-8 |
| InChI | InChI=1/2C8H12.CHF3O3S.Rh/c2*1-2-4-6-8-7-5-3-1;2-1(3,4)8(5,6)7;/h2*1-2,7-8H,3-6H2;(H,5,6,7);/p-1/b2*2-1-,8-7-; |
Bis-(1,5-cyclooctadiene)-rhodium trifluoromethanesulfonate - Physico-chemical Properties
| Molecular Formula | C17H24F3O3RhS |
| Molar Mass | 468.34 |
| Melting Point | 159°C (dec.)(lit.) |
| Boling Point | 153.5°C at 760 mmHg |
| Flash Point | 31.7°C |
| Water Solubility | insoluble |
| Solubility | Soluble in chloroform |
| Vapor Presure | 4.25mmHg at 25°C |
| Appearance | Solid |
| Color | dark red |
| Exposure Limit | ACGIH: TWA 1 mg/m3NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3 |
| Storage Condition | Inert atmosphere,Room Temperature |
| Sensitive | Air Sensitive |
| MDL | MFCD00143752 |
Bis-(1,5-cyclooctadiene)-rhodium trifluoromethanesulfonate - Risk and Safety
| Hazard Symbols | Xi - Irritant |
| Risk Codes | 36/37/38 - Irritating to eyes, respiratory system and skin. |
| Safety Description | 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. |
| WGK Germany | 3 |
| TSCA | No |
| HS Code | 28439000 |
| Hazard Note | Irritant |
Bis-(1,5-cyclooctadiene)-rhodium trifluoromethanesulfonate - Introduction
Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate is a platinum group metal complex with the chemical formula [C8H12]2Rh(CF3SO3). Here is some information about the compound:
Nature:
- Bis(1,5-cyclo octadiene)rhodium(I) trifluoromethanesulfonate is a red-brown solid in an organic solvent.
-It is soluble in organic solvents, but almost insoluble in water.
-It is sensitive to air and water, and should be stored and operated under an inert atmosphere.
Use:
- Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate are commonly used as catalysts, especially in organic synthesis.
-It has a wide range of applications in the synthesis of organic compounds, polymers and hybrid materials.
-As a catalyst, it can catalyze various chemical reactions, such as hydrogenation of olefins, asymmetric synthesis, etc.
Preparation Method:
- Bis(1,5-cyclo octadiene)rhodium(I) trifluoromethanesulfonate are generally prepared by synthetic methods.
-A common preparation method includes reacting rhodium fluoromethanesulfonate with 1,5-cyclooctadiene and ammonium rhodium oxide to generate Bis (1,5-cycloctadiene) rhodium(I) trifluoromethanesulfonate.
Safety Information:
- Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate need to be careful when using and operating because it is sensitive to air and water.
-Appropriate safety measures should be taken during operation, such as wearing appropriate personal protective equipment and operating in a well-ventilated area.
-Due to its toxicity and reactivity, the compound should be stored in a sealed container and away from flammable materials and strong oxidants.
-When using this compound, please refer to more detailed safety and operation guidelines, and follow the standard operating procedures of the laboratory.
Nature:
- Bis(1,5-cyclo octadiene)rhodium(I) trifluoromethanesulfonate is a red-brown solid in an organic solvent.
-It is soluble in organic solvents, but almost insoluble in water.
-It is sensitive to air and water, and should be stored and operated under an inert atmosphere.
Use:
- Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate are commonly used as catalysts, especially in organic synthesis.
-It has a wide range of applications in the synthesis of organic compounds, polymers and hybrid materials.
-As a catalyst, it can catalyze various chemical reactions, such as hydrogenation of olefins, asymmetric synthesis, etc.
Preparation Method:
- Bis(1,5-cyclo octadiene)rhodium(I) trifluoromethanesulfonate are generally prepared by synthetic methods.
-A common preparation method includes reacting rhodium fluoromethanesulfonate with 1,5-cyclooctadiene and ammonium rhodium oxide to generate Bis (1,5-cycloctadiene) rhodium(I) trifluoromethanesulfonate.
Safety Information:
- Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate need to be careful when using and operating because it is sensitive to air and water.
-Appropriate safety measures should be taken during operation, such as wearing appropriate personal protective equipment and operating in a well-ventilated area.
-Due to its toxicity and reactivity, the compound should be stored in a sealed container and away from flammable materials and strong oxidants.
-When using this compound, please refer to more detailed safety and operation guidelines, and follow the standard operating procedures of the laboratory.
Last Update：2024-04-10 22:29:15
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CAS: 99326-34-8
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Product Name: Bis(1,5-cyclooctadiene)rhodium(I) trifluoro methanesulfonate Request for quotation
CAS: 99326-34-8
Tel: 0086-13605431940
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Mobile: +86-13605431940
QQ: 56860987
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CAS: 99326-34-8
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